OPTICAL MODELING OF FLUORINE DOPED TIN OXIDE FILMS FOR SPECTRALLY SELECTIVE APPLICATIONS
DOI:
https://doi.org/10.58216/kjri.v9i1.109Abstract
SnO2: F films are widely used for solar cell applications as the front electrode as well as other applications such as electrochromic and displays. The optical design of these and other applications need knowledge of optical constants. In this study we used the dielectric constant of a combined Drude and Lorentz to model the optical behaviour of SnO2: F. To do this, we used the fitting parameters from existing literature. From the model we got n and k values which we inserted into Fresnel R and T calculator and computed R and T spectra over the 300nm -2500nm wavelength range using Fresnel’s equations. We plotted n, k, T and R for different values of plasma frequency, and damping parameter, . The films exhibited very high visual transmittance and high infrared reflectance. The results implied the possibleness of the films to be employed as spectrally selective coating materials.
Downloads
References
C. Granqvist and A. Hultåker, "Transparent and Conducting ITO Films: New Development and Applications," pp. 1-5, 2002.
Hecht, D. Hu and G. Irvin, "Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene and Metallic Nanostructures," Advanced materials, pp. 1482-1513, 2011.
B.-Y. &. Jeong, M.-C. &. Moon, T.-H. &. Lee, W. &. Myoung, J.-M. &. Hwang, Jeoung-Yeon, Seo and Dae-Shik., "Transparent conductive Al-doped ZnO films for liquid crystal displays.," Journal of Applied Physics, no. 99, pp. 124505-124505., 2006.
Weis and Martin., "Transparent Electrodes for Flexible Organic Light-Emitting Diodes and Displays.," Display and Imaging., pp. 46-68, 2015.
P. K. Biswas, "Study of solar radiation at various incident angles on soft chemistry based transparent conducting oxide (TCO) coated window glass," Journal of Fundamentals of Renewable Energy and Applications, pp. 57-65, 2018.
L. E. Runnerstrom, A. Llorde, D. S. Lounisac and J. D. Milliron, "Nanostructured electrochromic smart windows: traditional materials and NIR-selective plasmonic nanocrystals," Royal society of chemistry, pp. 10555-10572, 2014.
S. Boscarino, I. Crupi, S. Mirabella, F. Simone and A. Terassi, "TCO/Ag/TCO transparent electrodes for solar cells application," Applied Science A, p. 1287–1291, 2014.
K. Angelov, H. Komitov and A. Mustafov, "Transparent conductive oxides and their shielding efficiency against electromagnetic interferences," pp. 111-115, 2015.
B. Karmakar, Functional Glasses and Glass-Ceramics, United Kingdom: Butterworth-Heinemann, 2017.
July 2019. [Online]. Available: https://en.wikipedia.org/wiki/Electrochemical_cell.
Y.-S. Shim, H. G. Moon, D. H. Kim, H. W. Jang, C.-Y. Kang, Y. S. Yoon and Soek-JinYoona, "Transparent conducting oxide electrodes for novel metal oxide gas sensors," Elsevier, Sensors and Actuators B, pp. 357-363, 2011.
R. Mishra, K. Sheo and S. Prakash, "Optical and gas sensing characteristics of tin oxide nano-crystalline film," Journal of Ovonic Research, pp. 77-85, 2009.
Shamala, Murthy and Narasimha, "Studies on Tin oxide Films Prepared by Electron Beam Evaporation and Spray Pyrolysis Methods," Indian Academy of Sciences, Bull. Material Sci., pp. 295-301, 2004.
Chitra, Takwale, Bhide, Shailaja and Kulkarni, "Effect of Sn incorporation on the growth mechanism of sprayed SnO2 films.," Amerrican Instute of Physics, pp. 73-82, 1991.
Z. Shanting, "Study of fluorine-doped tin oxide (FTO) thin films for photovoltaics applications," Materials Universite Grenoble, p. 40, 2017.
Z. Wang, C. Chen, K. Wu, H. Chong and H. Ye, "Transparent conductive oxides and their applications in near infrared Plasmonics," 2019.
G. Roy, "Criteria for choosing Transparent conductors," MRS Bulletin, pp. 52-57, 2000.
G. Dobrikov, M. Rassovska, N. Andreev, S. Boyadzhiev, K. Gesheva, T. Ivanova, P. Sharlandjiev and D. Nazarowa, "Development of transparent heat mirrors based on metal oxide thin film structures," Thin Solid Films, pp. 1091-1094, 2009.
R. W. Ronard, "Thin-film Coatings: Understanding key design principles of antireflection coatings," Laser Focus World, 2016.
A. Thelen, "Energy Related Optical coatings," Optical coating laboratory, pp. 65-80, 1981.
K. Nakataa and A. Fujishima, "TiO2 photocatalysis:Design and applications," Journal of Photochemistry and photobiology C, pp. 169-189, 2012.
H. Ivar, "Indium-Tin-Oxide Thin Films:Basic Optical Properties and applications to Energy Efficient Windows," Chalmers University of Technology, Goteborg, Sweden, 1984.
C. Maghanga, Preparation and Characterisation of a Spectrally Selective Reflector Surface Based on TiO2:Nb Thin Films., Eldoret: Moi University, 2009.
J. (. Wanga and D. Shi, "Spectral selective and photothermal nano structured thin ï¬lms for energy efficient windows," Applied Energy 208, pp. 83-96, 2017.
F. Mark, Optical Properties of Solids, New York: Oxford University Press, 2001.
C. G. Ribbing, Introduction to Material Optics, a Compendium, Sweden: Uppsala University, 2002.
S. JI and R. NAB, "Effect of Processing on the Electrical Properties of Spray-Deposited SnO2:F Thin Films.," Journal of Applied Science, pp. 672-677, 2008.
R. Swinepoxes, "Determination of Thickness and Optical Constants of Armorphous Silicon," Journal of Physics, p. 1214, 1983.
W. Theiss and W. Teiss(Ed.), "Scout Thin film Analysis Software Handbook, Hard and Software," Aachen, Germany, pp. 54-57, 2001.
J. S. Maudes and T. Rodrigues, "Sprayed SnO2 films: Growth Mechanism and film Structure Characterization," Thin film solids, pp. 183-189, 1980.
M. J. Mageto, C. Maghanga, M. Mwaburi and H. Jafri, "Transparent and conducting TiO2:Nb thin films prepared by spray pyrolysis technique," American Research Journal of Physics, p. 63, 2015.
D. Mergel and Z. Qiao, "Dielectric modelling of the optical spectra of thin In2O3:Sn films," Journal of Physcics D: Applied Physics, pp. 794-801, 2002.
M. J. Mageto, C. Maghanga and M. Mwamburi, "The Lorentz Osillator Model simulation Illustrating a Broad Maximum in the Bulk Reflectance for Frequencies Just Above the Resonance Frequency," The African Review of Physics, pp. 95-105, 2012.
F. Wooten, Optical Properties of Solids, New York: Academic Press, 1972.
W. Q. Hong, "Extraction of extinction coefficient of weak absorbing thin films from special absorption," Journal of Applied Physics D: Applied Physics, vol. 22, pp. 1384-1385, 1989.
C. Granqvist, Handbook of Inorganic Electrochromic Materials, the Netherlands: Elsevier, Amsterdam, 1995, pp. 265-275.
E. Shanthi, V. Dutta, A. Banerjee and K. Chopra, "Electrical and Optical Properties of undoped and antimony-doped tin oxide films," Journal of Applied Science, pp. 6243-6253, 1980.
S. Zhang, "Study of fluorine-doped tin oxide (FTO) thin fims for photovoltaics applications," Materials Universite Grenoble Alpes, 2017.
I. Hamberg and C. Granqvist, Appl. Phys.
Granqvist, private communication:E-beam evaporated ITO is produced commercially by OCLI, california, 1984.